Mercury's surface temperatures are For a cylinder containing dangerous goods, the label must be displayed on or near the shoulder of the cylinder as shown below [Subsection 4.10(3)]. Subsidiary: In NetSuite each subsidiary record should be assigned with the nexuses in which it must pay taxes. WebClassification of dangerous goods is broken down into nine classes according to the type of danger materials or items present, click on a class to read more details; 1. If you use UN 3077 or UN 3082, the proper shipping name shall also be supplemented with technical names. Oxidizing 6. The Primary class is shown first, with the subsidiary classes in brackets. You need to ask yourself the following questions first and follow the above rules to determine accurate proper shipping names for your products. Wastes: If the product is a waste, then the shipping name is either preceded or followed by the word waste. (b) Except as provided in this subpart, the basic description specified in paragraphs (a)(1), (2), (3), and (4) of this section must be shown in sequence with no additional information interspersed. ; UN 1224, KETONES, LIQUID, N.O.S, Example: UN 1993 FLAMMABLE LIQUIDS, N.O.S. Assigning a substance into a hazard class is usually done by the consignor. "6%X3$dl@7H,d100K@ ^/ As such, the mixture would be assigned the shipping name FLAMMABLE LIQUID, N.O.S.. In this article, we will share with you some rules you need to follow when choosing UN numbers and proper shipping names. The subsidiary class is the other class that further identifies the hazards of the dangerous goods. Although every effort is made to ensure the accuracy, currency and completeness of the information, CCOHS does not guarantee, warrant, represent or undertake that the information provided is correct, accurate or current. Browse our full range of workplace health and safety products and services. Product mixture that consists of multiple dangerous goods: If the shipping name is not a specific name, then the technical name of the most dangerous substance needs to be provided in brackets as required in Special Provision 16 in Schedule 2. Examples of such products are: 3. N.O.S. You need to choose a UN number (usually, 4 digits) and a proper shipping name from Dangerous Goods List that can most accurately describe your dangerous goods. (i) The words Class or Division may be included preceding the primary and subsidiary hazard class or division numbers. 2. The requirements for the display of the dangerous goods safety marks also depend on: Labels and placards are diamond shaped (also referred to as square on point) and must be displayed as illustrated below. 1289 0 obj <>/Filter/FlateDecode/ID[]/Index[1273 31]/Info 1272 0 R/Length 79/Prev 99077/Root 1274 0 R/Size 1304/Type/XRef/W[1 2 1]>>stream Information on how to do the assignment is provided in Section 2.36 of Part 2. colour used for the safety mark (e.g., orange, red, blue). X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? 28-35-189a - 28-35-189a - Advance notification of transport of nuclear waste, Kan. Admin. The size (i.e., capacity) of the means of containment itself also determines whether a label or placard is required. The metal is obtained by heating cinnabar in a current of air and condensing the vapour. Code 246-231-140 - 246-231-140 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. For example, for a flammable mixture consisting of two or more alcohols, both entries below may be applicable. are classified in the Class 1 hazard class. Other requirements may be listed in other sections, regulations, Codes, or Acts that are not listed in this table. This placard is not mandatory, but it is permitted on a large means of containment (greater than 450 L) instead of any other placard when the containment has: - one or more dangerous goods that require different hazard class placards, - the dangerous goods are contained in two or more small means of containment, AND - the shipment consists of only the following dangerous goods classified in: NOTE: The TDG Regulations has specified circumstances when this placard is not allowed to be used. Are there other requirements for labels on a small means of containment? Download the OSH Answers app for free. Which one is the correct one? Depending on the classification for a dangerous good, one or more of the following safety marks may be required on a large means of containment: NOTE: Generally speaking, a placard must be displayed for each of the dangerous goods transported in a large means of containment regardless of the quantity. WebListing, classification and packing Mercury (UN 2809): Subsidiary risk 6.1 Transmitted by the expert from Germany Introduction 1. NOTE: See further belowin the table for placard requirement when the hazard class is 1.1, 1.2, 1.3, 1.4 or 1.5 are above a certain threshold of gross mass/number of articles. Powdered metals. 64-23-14 - 64-23-14 - Transportation of Radioactive Material. When a consolidation bin is used, the class of each dangerous good contained in the bin must be marked on a tag or on a fixed display device that is attached to the bin. Please also see the following documents in this series: The purpose of dangerous goods safety marks is to: Dangerous goods safety marks are required when the good that is being transported: The TDG Regulations (Part 4) specify that all safety marks must be: Responsibilities for dangerous goods safety marks depend on whether the handler of the dangerous goods is the: Before the goods are loaded on the means of transport (i.e., vehicle, truck), the consignor or importer must: Misleading safety marks are dangerous goods safety marks that might be deceptive, ambiguous, or provide false information about the presence or nature of any dangers. (a) The shipping description of a hazardous material on the shipping paper must include: (1) The identification number prescribed for the material as shown in Column (4) of the 172.101 table; (2) The proper shipping name prescribed for the material in Column (2) of the 172.101 table; (3) The hazard class or division number prescribed for the material, as shown in Column (3) of the 172.101 table. (ii) The hazard class need not be included for the entry Combustible liquid, n.o.s.. Go to Setup > company > Subsidiaries. For example: UN 1993, Flammable liquids, n.o.s. For more details, consult the legislation directly. Packing Group This column gives the packing groups of the dangerous goods. 1. A placard is used for a large means of containment whose capacity is more than 450 L. The marks for safety for each TDG class are shown in the OSH Answers document Transportation of Dangerous Goods (TDG) - 9 Classes. Self-heating solid, corrosive, organic, n.o.s. Figure 4: Placard requirements and placement for compartmentalized means of containment. A label is used for a small means of containment whose capacity is 450 L or less. Where or how do I find the above information? Column 6 Special Provisions This sign must be displayed at or next to each entry way of the large means of containment (greater than 450 L) when the containment is fumigated with a dangerous good. The most appropriate designation for the dangerous goods must be selected based on each class, UN number and packing group established per the classification requirements of clause 4.5. a document that explains how the dangerous goods were classified. Example 1: UN 1993, FLAMMABLE LIQUID, N.O.S (contains methanol and acetone); Example 2: UN 2902, PESTICIDE, LIQUID, TOXIC, N.O.S. Based on the definition for classification, a competent person must determine the following before a classification can be assigned to a dangerous good: Use all three schedules as listed in the TDG Regulations. Services Main Page. See the images below for examples of how to place the dangerous goods placards on large means of containments such as a highway tank (Figure 3), and compartmentalized means of containment (Figure 4). Determine the shipping name: Check if the product name is listed in Schedule 1 or Schedule 3. (4) The packing group in Roman numerals, as designated for the hazardous material in Column (5) of the 172.101 table. WebClasses 1 to 9 Col. 1 Col. 2 Col. 3 Col. 4 Col. 5 Col. 6 Col. 7 Col. 8 Col. 9 Col. 10 UN Number Shipping Name and Description Class Packing Group/ Category SOR/2008-34 MERCURY FULMINATE, WETTED with not less than 20 per cent water, or mixture of alcohol and water, by mass 1.1A UN0136 II 0 75 Forbidden Forbidden A substance, mixture, or article that is a marine pollutant and does not meet the classification criteria for inclusion in any other hazard class shall be declared under either UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, n.o.s. See table 1 below for placard requirements. The smallest planet in our solar system and nearest to the Sun, Mercury is only slightly larger than Earth's Moon. Access to this website What safety marks are required on a small means of containment (capacity 450L or less)? CHLORINE DIOXIDE is an example of a product that is forbidden by all routes of transportation as indicated in Schedule 3 with an entry of Forbidden in Column 2 - Hazard Class. Product usage (e.g., pesticide, adhesive, fuel, etc. If a mixture or solution is composed of a single predominant substance mentioned in the Dangerous Goods List and one or more substances not subject to DG classification, the mixture shall be assigned to the Proper Shipping Name of the predominant substance mentioned in the Dangerous Goods List by adding the qualifying words "MIXTURE" or "SOLUTION" unless: Example: UN 1090 ACETONE SOLUTION, or UN 1090 ACETONE 75% SOLUTION. Chemical family name (e.g., alcohol, ketone, etc. EDT. Founded in 1961 and headquartered in Los Angeles, Mercury has assets in excess of $4 billion, employs 4,500 people and has more than 8,000 independent agents in 11 states (Arizona, California, Use the shipping name and its corresponding data (UN number, class, packing group/category) in Schedule 1 to assign the classification to the dangerous good. Note: The NA numbers in the 49 CFR are not permitted in Canada. Note: The information below is provided as guidance only. Which technical names shall be given in parenthesis for generic entries and N.O.S entries? endobj 1. Peroxides. Regs. WebSubsidiary hazards must also be listed with the Basic Description. The packing group for a dangerous good is determined by using the laboratory test data and comparing it to the criteria in Part 2. Image from Transport Canada. Dangerous goods can present 1 or more of the hazards represented by Class 1 to 9 with some classes split into divisions. Who has responsibilities for dangerous goods safety marks? Consult Schedule 3 for the shipping name that most precisely describes the dangerous goods. if applicable, the technical name of the dangerous goods, the classification of the dangerous goods, and. Methylmercury and other organic compounds. Marine Pollutants: From the surface of Mercury, the Sun would appear more than three times as large as it does when viewed from Earth, and the sunlight would be as much as seven times brighter. NOTE: This category B mark must be displayed instead of the Class 6.2 label. You may also find an expert in CSP business directory below. If you have questions or need any help, please contact our sponsor. Products and The type of packaging and destination marks may be entered in any appropriate manner before or after the basic description. ;imX'1r9-Ttomh1!u~cSyK,v=d+2Cl>AmY\t%v|a&H%dl>; CbtgspL4nj(|c24O?DY_L[;!/aw=yAcC)fMZEnti ]~Mal};jv|y{D}odxh*ap-UDw,EY"h7!G07znrn83Qa=Xre:NWMg]3|u`gho7Ay0Cgh!7tf16+OIXe"m>GNkhhu&.7f{,M` =WaJ`I{W2O_eBX;96$ljWt8 Dangerous Goods of Class4.1, Packing Group II, not listed above, Magnesium or Magnesium alloys, with more than 50% magnesium, in pellets, turnings or ribbons, Naphthalene, crude or Naphthalene, refined, Titanium sponge granules or Titanium sponge powders, Dangerous Goods of Class4.1, Packing GroupIII, not listed above, Organometallic substance, solid, pyrophoric, water-reactive, Organometallic substance, liquid, pyrophoric, water-reactive, Phosphorus, white or Phosphorus, yellow, dry or Phosphorous, yellow, in solution or Phosphorous, yellow, underwater, Dangerous Goods of Class4.2, Packing Group I, not listed above, Potassium sulphide, anhydrous or Potassium sulphide, with less than 30% water of crystallization. See Section 2.5. The labelling requirements for an overpack depend on whether the labels can be seen through the overpack. Generally, a large means of containment must have four placards (one on each side, one on the front and one in back). This communication is accomplished by the: Note that the difference between labels and placards is their size. The classes in which the dangerous goods are included are ranked in order of precedence in accordance with Section 2.8 to determine the primary class and the potential subsidiary class or classes; The potential PG is ), MARINE POLLUTANT. For example, based on the above information from Schedule 1 we have the following information for UN1203: Schedules 1 and 3 will also indicate if any shipping routes are forbidden. The subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. By using the information provided in the HMT, you can correctly describe the hazardous materials shipment. The picture below shows hazard symbols for Class 4 dangerous goods. We expect this update to take about an hour. They also need to be included in Dangerous Goods Declaration and the section 14 of Safety Data Sheets. Who is responsible for classifying a dangerous good? You may experience longer than usual wait times or partial service interruptions. If a substance is included in more than one class or packing group, its classification is determined in the following manner: Phosphorus sesquisulphide, free from yellow and white phosphorus, Rubber scrap or Rubber shoddy, powdered or granulated, not greater than 840 mm and rubber content greater than 45%. The following provisions also apply: (i) For Class 1 materials, the quantity must be the net explosive mass. Explosives 2. NOTE: The table below is for guidance purposes only. The flash point must be indicated for materials with a primary or subsidiary Class 3 hazard. Definition for a solution When the ingredients in a mixture are completely dissolved. International Civil Aviation Organization (ICAO) Technical Instructions for the transport of dangerous goods by air, International Maritime Dangerous Goods (IMDG) Code for the transport of dangerous goods by ship, or. For example: UN1993, FLAMMABLE LIQUID, N.O.S. If the product is not listed by specific name in Schedule 1 or 3, check if it meets any of the criteria for the hazard classes in Part 2 - Classification. For example, if you have a product for which you determined that the shipping name will be FLAMMABLE LIQUID, N.O.S. %PDF-1.4 The following packing group always takes precedence irrespective of hazards: The following hazard class always takes precedence irrespective of packing groups: If above two rules do not apply, please refer to the following hazard precedence table to choose primary hazard. WebThe symbol P used in this schedule means that the handling, offering for transport, and transporting of the dangerous goods by rail is prohibited. Elevated temperature liquid, n.o.s., at or above 100C (212F) and below its flashpoint including molten metals, molten salts, etc. Determine the primary class, subsidiary class(es) and packing group by using section 2.8 - Precedence of Classes in Part 2, Classification. In this case, the product is not TDG regulated and the product does not need to comply with the TDG Regulations. Azides. The rules are set out in a table, the segregation table in 7.2.4, and also have to be applied in respect of any subsidiary class. What is its predominant hazard substance and primary hazard? 0400-20-10-.30 - 0400-20-10-.30 - PACKAGING AND TRANSPORTATION OF RADIOACTIVE MATERIAL. For example, both gasoline and diesel are listed by their name in Schedule 1. Mercury and its compounds. What information is needed for classification? Figure 2: Safety marks on a small means of containment such as a package Note 1: The orientation marks for liquids are optional for road transport, but mandatory for air transport. Are the classifications for other modes or international shipments the same? Yes. For detailed information, please see Part 2 of TDG Regulations. b) The laboratory test results show the product falls into one class and one packing group. Code tit. sponsor this page to leave your contact info on this page.. When the shipping name is not a specific name such as a family name, then these shipping names are followed by N.O.S. (contains Xylene and Benzene), 3, II. Definition for a mixture a product that contains two or more ingredients. the other class that further identifies the hazards of the dangerous goods. Special Provisions This column gives the special provisions that apply to the dangerous goods. See Section 4.23 of Part 4 in the TDG Regulations. Generally, the shipping name should be selected in the following hierarchical order: 1. Some of the classes can be further divided into divisions, e.g., Class 1, while others do not have sub-divisions, e.g., Class 3. Inhalation Hazard words for Class 6.1 and Class 2.3 dangerous goods, Category B Mark for UN3373 dangerous goods, Package certification marks (if required), Placard for the primary hazard class on each side and each end (total of four) for each dangerous good. You may also find an expert in CSP business directory below. See Section 2.4. The ICAO Technical Instructions, as well as Part 12, Air, of the TDG Regulations must be consulted for all shipments by air. The data below is an example showing UN1203, GASOLINE. Webmercury and mercury compounds: 0.1 mg/m3 (TWA), skin - ACGIH Threshold Limit Value (TLV): inorganic and metallic mercury, as Hg: 0.025 mg/m3 (TWA) skin, A4 Not 120.790 - 120.790 - Advance Notification of Shipment of Nuclear Waste, 180 Neb. Other dangerous goods safety marks that may be required for a shipment of dangerous goods are summarized in Table 2 below. Gross quantity of Class 1.4 (except Class 1.4S) is 1000 kg or less, Class1.1, 1.2, 1.3 or 1.5 explosives that are not subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 10 kg, Class1.1, 1.2, 1.3 or 1.5 explosives that are subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 1000 articles. Also, regardless of the quantity of dangerous goods on board, the primary class placard for each of the dangerous goods in a large means of containment must be displayed on each side and on each end of the large means of containment or means of transport. For information on COVID-19 updates, please visit Canada.ca/coronavirus. Dangerous goods that can be shipped under this exemption will have an excepted quantity code of E1, E2, E3, E4, or E5 in Column 6(b) of Schedule 1 of the TDG Regulations. means Not Otherwise Specified. If the dangerous good is an explosive or radioactive material, it must be classified as required by other regulatory authorities. Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers The following state regulations pages link to this page. ), code or number for a particular hazard (e.g., 1- Explosive, 2 - Gases, 3 - Flammables), Provide quick identification of the dangerous goods in an emergency (e.g., release of dangerous goods during an incident), Communicate the nature and degree of the danger, Quickly determine if dangerous goods in a mixed load are incompatible, is determined to be a dangerous good under the TDG Regulations, and, displayed against a background of contrasting colour, made of durable, weather-resistant material that will resist coming detached or fade, Select the correct label(s) for each small means of containment (e.g., drum, package, overpack), Make sure that each small means of containment (e.g., package or container) of dangerous goods is properly labelled and marked, Select the correct placards and other safety marks for each large means of containment (e.g., tanker), Display the placards and other safety marks, or provide the appropriate placards to the carrier (when the means of containment or means of transport belongs to the carrier), Confirm that the safety marks are correct, Make sure the safety marks are displayed and remain displayed during transport, Replace safety marks when during transport they are stolen, lost, or defaced, Provide and display appropriate safety marks when the contents of the shipment change (e.g., new consignments are loaded on the means of transport), Remove or cover safety marks when the dangerous good is no longer present. Subscribe to Free Newsletter The primary class is the class of dangerous goods that takes precedence over any other class. Nitrites and their mixtures. How does the consignor determine the classification for a dangerous good? "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#b{ogw~0B"ty'{~Oi"v?`"DqXmImPiww#R{;?j}J3]0{ ?>]|YlbE#SsBsz/E":}NCg7ON2P5N}s/w?9LO?zZ^/1BWu~N"r~!P;1FAS*:hzQHo _+3l3E6FAsmH}]fwcxoCcbb,!7cTvt{o&h: foC"uF2c;&4m;vx?=8 ga ` !%6M`Wn-@lM;#={CSaW+r:&|gB7/ndJlXqFxs1}n]N:=jd#]5$b{9NF">OL_7!y;3~*cQlCek4o6 eeGn:9P_mO}W'^q7{X,V{TFi8Qj eg/od{QVg{*Ky3n_0ht vv@9g;OkRz~w}79!^C:[7C .{;T/tUOB9x|]\;Q7W{!~uhM Code. 391-3-17-.06 - Rule 391-3-17-.06 - Transportation of Radioactive Material, 410 Ind. Access to this website It can cause genetic deformities and alteration in the genetic material of a person. Proper shipping name is the standard technical name to describethe hazard properties and the composition of dangerous goods. What is the purpose of dangerous goods safety marks? It is determined according to the specification in section 2.8 and the Precedence of Classes Table which is provided in Part 2. It also produces the MerCruiser line of sterndrivesand inboard motors. in the case of infectious substances, a doctor, scientist, veterinarian, epidemiologist, genetic engineer, pathologist, nurse, coroner, or laboratory technologist or technician. : AC413650000; AC413650025; AC413650050; AC413651000; AC413655000 CAS No 7783-35-9 Synonyms Mercuric sulfate Setup. For the dangerous goods other than Class 1 DG, a Conveyance Permit (For Dangerous Goods other than Class 1 Dangerous Goods) is required. WebClass 1 Explosives; Class 2 Gases; Class 3 Flammable liquids; Class 4 Other Flammable Substances; Class 5 Oxidizing Substances & Organic Peroxides; Class 6 Ark. Example: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. See Section 1.17 in the TDG Regulations. What safety marks are required on a large means of containment (capacity 450L or more)? 4 0 obj Always consult the legislation that applies in your situation. Depending on the classification of the dangerous good, one or more of the following safety marks may be required on a small means of containment: See Figure 2 for an example of dangerous goods safety marks on a small means of containment such as a package. These words must be displayed on a small or large means of containment when dangerous goods are shipped or imported for the hazard classes: Small means of containment: These words must be displayed next to the shipping name. 619 of 2001 Notation Ceiling-C Ceiling value is a limit value above which exposure Dangerous goods that can be shipped under this exemption will have a limited quantity index greater than 0 in Column 6(a) of Schedule 1 of the TDG Regulations. endstream endobj startxref What types of other dangerous goods safety marks may be required? 157.94 - DHS 157.94 - Operating controls and procedures. Admin. 1273 0 obj <> endobj View Past Newsletter, http://www.unece.org/fileadmin/DAM/trans/danger/publi/adr/adr2011/English/Part3.pdf, http://www.phmsa.dot.gov/filename/Marine_Pollutant_Guidance.pdf, Biocides and Biocidal Product Regulations, Example: UN 1133 ADHESIVES containing flammable liquids; UN 1263, PAINT, Example: UN 1987 ALCOHOLS, N.O.S. This mark is displayed on small means of containment filled with infectious substances that are assigned to UN3373, Biological Substance Category B. If the product's name (e.g., chemical name) is listed in Schedule 1 or 3 then the primary hazard class is in Column 3 of Schedule 1 and in Column 2 of Schedule 3 for that shipping name. It exists in several forms: Elemental (metallic) mercury. (d) Technical and chemical group names may be entered in parentheses between the proper shipping name and hazard class or following the basic description. (vii) for dangerous goods that are subject to special provision 23, the words toxic by inhalation or toxic inhalation hazard or toxique par inhalation or toxicit par inhalation; Examples of classification descriptions of dangerous goods are: UN1214, ISOBUTYLAMINE, Class 3, Subsidiary Class (8), II, UN1214, ISOBUTYLAMINE, Class 3(8), Packing Group II, UN3381, TOXIC BY INHALATION LIQUID, N.O.S., Class 6.1 PG I, UN 1075 LIQUEFIED PETROLEUM GASES (propane); Not odourized, Class 2.1. However, if these two substances were mixed, the resulting mixture of these two products would still be regulated as a dangerous good. c) The laboratory test results show the product falls into more than one class or packing group. If a substance is The symbol P used in this schedule means that the handling, offering for transport, and transporting of the dangerous goods by rail is prohibited. More than one subsidiary class is possible. Shipping name is the name of the dangerous good as it appears in column 2 of Schedule 1. 28-35-504 - 28-35-504 - Advance notification of shipment of certain types of licensed or registered material, Kan. Admin. For example: the mixture is liquid and homogeneous and the ingredients will not separate (e.g., no visible solids or two different phases such as you would observe when oil and water are mixed). Class 3 Packing Group III. UN Number This column gives the UN number assigned to the dangerous goods under the UN system. Note: A mixture or solution that is not mentioned in the Dangerous Goods List and that is composed of two or more dangerous goods shall be assigned one entry that most precisely describes the solution or mixture. WebProduct Name Mercury(II) sulfate Cat No. when all of the dangerous good safety marks can be seen through the overpack for each class of dangerous goods that is inside it, no additional labels or safety marks are required. ), 2. Electronic Code of Federal Regulations (e-CFR), Subtitle B - Other Regulations Relating to Transportation, CHAPTER I - PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION, SUBCHAPTER C - HAZARDOUS MATERIALS REGULATIONS, PART 172 - HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, TRAINING REQUIREMENTS, AND SECURITY PLANS, Ariz. Admin.